New Bitter-Tasting Hemiterpene Glycosides from the Japanese Fern Hymenophyllum barbatum.

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New bitter-tasting hemiterpene glycosides from the Japanese fern Hymenophyllum barbatum.

Hymenosides G--J were newly isolated from the Japanese fern Hymenophyllum barbatum, in addition to hymenosides A--F. The structures of hymenosides were elucidated by extensive two-dimensional nuclear magnetic resonance and/or chemical evidence. The structures of those aglycones were divided into three types, 1,4-dihydroxy-2-hydroxymethyl-but-2-ene, 1,4-dihydroxy-2-methyl-but-2-ene, and 3-hydrox...

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In the course of investigation of the bitter-tasting substances of the Japanese fern Hymenophyllum barbatum belonging to the family Hymenophyllaceae, six new hemiterpene glucosides called hymenosides A-F (1-6) have been isolated from the methanol extract, together with an acyclic bis-bibenzyl derivative, perrottetin H. This paper deals with the structure elucidation of the newly isolated glucos...

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ژورنال

عنوان ژورنال: Chemical and Pharmaceutical Bulletin

سال: 2001

ISSN: 0009-2363,1347-5223

DOI: 10.1248/cpb.49.1567